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Yes, that's Pharrell behind the mustache.
He, along with Julianne Moore, artist Jeff Koons, and Malia Jones were photographed by David LaChapelle as part of the campaign for their partnership with Kiehl's on its Earth Day 2010 initiative. The celebs are each touting limited-edition labels on the beauty company's organic Açaí Damage-Protecting Toning Mist. 100% of net proceeds (up to $200,000) from the sales of this limited-edition packaged product will go to the Rainforest Alliance.
Doesn't Julianne Moore always look lovely?